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. 2018 Jul 18;140(28):8624-8628.
doi: 10.1021/jacs.8b03302. Epub 2018 Jul 10.

Dearomative Cascade Photocatalysis: Divergent Synthesis through Catalyst Selective Energy Transfer

Michael J James  1 , Jonas Luca Schwarz  1 , Felix Strieth-Kalthoff  1 , Birgit Wibbeling  1 , Frank Glorius  1
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Free article

Dearomative Cascade Photocatalysis: Divergent Synthesis through Catalyst Selective Energy Transfer

Michael J James et al. J Am Chem Soc. .
Free article

Abstract

The discovery and application of dearomative cascade photocatalysis as a strategy in complex molecule synthesis is described. Visible-light-absorbing photosensitizers were used to (sequentially) activate a 1-naphthol derived arene precursor to divergently form two different polycyclic molecular scaffolds through catalyst selective energy transfer.

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