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. 2000 Nov 8;122(44):11031-11032.
doi: 10.1021/ja0055110. Epub 2000 Oct 21.

Organoselenium-Based Entry into Versatile, α-(2-Tributylstannyl)vinyl Amino Acids in Scalemic Form: A New Route to Vinyl Stannanes

David B Berkowitz  1 , Jill M McFadden  1 , Esmort Chisowa  1 , Craig L Semerad  1
Affiliations

Organoselenium-Based Entry into Versatile, α-(2-Tributylstannyl)vinyl Amino Acids in Scalemic Form: A New Route to Vinyl Stannanes

David B Berkowitz et al. J Am Chem Soc. .
No abstract available

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Figures

Scheme 1
Scheme 1
Scheme 2
Scheme 2
Scheme 3<i><sup>a</sup></i>
Scheme 3a
aKey: (i) Pd2dba3, p-I-C6H4-NO2, THF (85%); (ii) DCl, D2O, Δ, then Dowex-50 (75%); (iii) I2, CCl4 (92%); (iv) H2C=CHSnBu3, Pd2dba3, Pfur3, NMP (65%) (v) DMAD, Δ then Br2, CCl4/KOtBu, DMF.
See this image and copyright information in PMC

References

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