Fluorescence of Nonaromatic Organic Systems and Room Temperature Phosphorescence of Organic Luminogens: The Intrinsic Principle and Recent Progress

Abstract

Following the development of photoluminescence systems with various compositions, some nontraditional structures, including nonaromatic organic systems as fluorophores and organic luminogens as the source of phosphorescence emission at room temperature, have attracted considerable attention for their advantages in biological and medical applications, and for the updated photophysical understandings in science. In this Review, the recent progress in understanding these organic compounds or polymers for fluorescence and phosphorescence is briefly summarized, with the aim of exploring the intrinsic principle of these novel photoluminescence systems and providing reasonable constructs for molecular design. Finally, some prospects are suggested for further development of this continually expanding area of research, with the coined concept of Molecular Uniting Set Identified Characteristic (MUSIC).

Keywords: fluorescence; intermolecular interaction; molecular uniting; packing mode; phosphorescence.