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Published Erratum
. 2018 Jan 26;9(6):1700.
doi: 10.1039/c7sc90080e. eCollection 2018 Feb 14.

Correction: Dye-sensitized electron transfer from TiO2 to oxidized triphenylamines that follows first-order kinetics

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Published Erratum

Correction: Dye-sensitized electron transfer from TiO2 to oxidized triphenylamines that follows first-order kinetics

Brian N DiMarco et al. Chem Sci. .

Abstract

[This corrects the article DOI: 10.1039/C7SC03839A.].

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Scheme 1
Scheme 1. Mechanism for the photoinitiation of the desired reaction. Visible light absorption by the ruthenium sensitizer induced rapid excited-state electron injection to the acceptor state of TiO2, kinj > 108 s–1. The oxidized sensitizer is then regenerated by triphenylamine (TPA) with a rate constant kreg. This sequence provides the reactants for the desired charge recombination reaction of the injected electron with the oxidized triphenylamine redox mediator (krec) that was quantified over a 0.5 eV change in driving force.

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