Facile and on-line colorimetric detection of Hg2+based on localized surface plasmon resonance (LSPR) of Ag nanotriangles

Abstract

A rapid and sensitive colorimetric detection method for the determination of Hg²⁺ has been successfully developed in this research. Citrate-functionalized silver nanotriangles (AgTrngs) were synthesized via one-pot sodium borohydride method with the edge-length range of 30 - 40 nm. The obtained AgTrngs were fully characterized using UV-Vis spectrophotometry, transmission electron microscopy (TEM), energy dispersed spectroscopy (EDS) and X-ray diffractometer. The efficiency of the developed sensor was optimum at pH= 8 due to interfering effect of H⁺ ions for Hg²⁺ under acidic conditions. The successful detection of mercury in aqueous solutions in the concentration range of 10 nmol L^-1-50 μmol L^-1 indicated the applicability of the developed sensor for effective monitoring and controlling the level of Hg²⁺ in industrial effluents. The ability of Hg²⁺ ion to interact with Ag and form the Hg-Ag alloy (amalgam) over the surface of AgTrngs resulted in an obvious color change from blue to violet. UV-Vis spectrophotometry showed that the sensor has the limit of detection (LOD) value of as low as 4 nmol L^-1 which was below the safety level of Hg²⁺ions (10 nmol L^-1) in drinking water. The proposed method can be used for on-line determination of Hg²⁺ in the complex aqueous solutions.

Keywords: Colorimetric sensor; Optical sensor; Silver nanostructures; Water pollution.