Understanding contact between platinum nanocontacts at low loads: The effect of reversible plasticity

Abstract

Metal nanocontacts play a critical role in atomic force microscopy, functional nanostructures, metallic nanoparticles, and nanoscale electromechanical devices. In all cases, knowledge of the area of contact, and its variation with load, is critical for the quantitative prediction of behavior. Often, the contact area is predicted using continuum mechanics models which relate contact size to geometry, material properties, and load. Here we show for platinum nanoprobes that the contact size deviates significantly from these continuum predictions, even at low applied loads and in the absence of irreversible shape change. We use in situ transmission electron microscopy (TEM) with matched molecular dynamics (MD) simulations to investigate the load-dependent size of the contact. Direct measurements of contact radius from MD and TEM exceed the predictions of continuum mechanics by 24%-164%, depending on the model applied. The physical mechanism for this deviation is found to be dislocation activity in the near-surface material, which is fully reversed upon unloading. These findings demonstrate that contact mechanics models are insufficient for predicting contact area in real-world platinum nanostructures, even at ultra-low applied loads.