Membrane fouling and performance of anaerobic ceramic membrane bioreactor treating phenol- and quinoline-containing wastewater: granular activated carbon vs polyaluminum chloride

Abstract

Although anaerobic membrane bioreactor (AnMBR) has been proposed for the treatment of phenolic wastewater, the membrane fouling is still a major obstacle. The effects of dosing of granular activated carbon (GAC) and polyaluminum chloride (PACl) on the treatment performance and membrane fouling of anaerobic ceramic membrane bioreactor were investigated for treating phenol- and quinoline-containing wastewater. The results suggested that the one-off dosing of GAC resulted in a decrease of protein/carbohydrate ratio, which might account for the aggravation of membrane fouling alongside with the decreased flocs size. Nevertheless, the substrate uptake rates (SUR) of phenol and quinoline, and the specific methanogenic activity of sludge at the GAC dosing stage of experimental reactor (R1) were 8.79 ± 0.63 mg phenol g^-1 MLVSS d^-1, 7.01 ± 0.09 mg quinoline g^-1 MLVSS d^-1 and 0.27 ± 0.01 g COD_CH4 g^-1 MLVSS d^-1, which were 1.69, 3.59 and 1.93 times higher than that of the control reactor (R2). The dosing of PACl reduced the membrane fouling rate by changing the floc structure of sludge, as well as the component of SMP and EPS. However, the substrate uptake rate of quinoline was declined. This work provides a comprehensive evaluation on the effect of GAC and PACl dosing on membrane fouling and performance of anaerobic ceramic membrane bioreactor treating phenol-and quinoline-containing wastewater.

Keywords: Anaerobic digestion; Anaerobic membrane bioreactor; Granular activated carbon; Membrane fouling; Phenol; Polyaluminum chloride.