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. 2018 Dec 21;20(24):8004-8008.
doi: 10.1021/acs.orglett.8b03579. Epub 2018 Dec 11.

A Highly Stable Organic Radical Cation

Mathilde Berville  1 , Jimmy Richard  1 , Monika Stolar  2 , Sylvie Choua  1 , Nolwenn Le Breton  1 , Christophe Gourlaouen  1 , Corinne Boudon  1 , Laurent Ruhlmann  1 , Thomas Baumgartner  2 , Jennifer A Wytko  1 , Jean Weiss  1
Affiliations

A Highly Stable Organic Radical Cation

Mathilde Berville et al. Org Lett. .

Abstract

Functionalization of a methylviologen with four methyl ester substituents significantly facilitates the first two reduction steps. The easily generated radical cation shows markedly improved air stability compared to the parent methylviologen, making this derivative of interest in organic electronic applications.

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