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. 2019 Jan 9;141(1):25-28.
doi: 10.1021/jacs.8b10212. Epub 2018 Dec 28.

Total Synthesis of Herquline B and C

Joshua B Cox  1 , Aoi Kimishima  1 , John L Wood  1
Affiliations

Total Synthesis of Herquline B and C

Joshua B Cox et al. J Am Chem Soc. .

Abstract

The total syntheses of (-)-herquline B (2) and a heretofore-unrecognized congener, (+)-herquline C (3), are described. The syntheses require 14 and 13 steps, respectively, and feature a key oxazoline reduction that sets the stage for piperazine construction.

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