Manganese-doped zinc oxide hollow balls for chemiresistive sensing of acetone vapors

Dongting Wang^{1

2}, Wenan Shang^{1

2}, Bingxue Zhang^{1

2}, Chunjie Jiang³, Fengdong Qu⁴, Minghui Yang⁵

Affiliations

¹ School of Chemistry and Chemical Engineering, Liaoning Normal University, Dalian, 116029, People's Republic of China.
² Key Laboratory of Marine Materials and Related Technologies, Zhejiang Key Laboratory of Marine Materials and Protective Technologies, Ningbo Institute of Materials Technology and Engineering, Chinese Academy of Sciences, Ningbo, 315201, China.
³ School of Chemistry and Chemical Engineering, Liaoning Normal University, Dalian, 116029, People's Republic of China. jiangcj@lnnu.edu.cn.
⁴ Key Laboratory of Marine Materials and Related Technologies, Zhejiang Key Laboratory of Marine Materials and Protective Technologies, Ningbo Institute of Materials Technology and Engineering, Chinese Academy of Sciences, Ningbo, 315201, China. fqu@nimte.ac.cn.
⁵ Key Laboratory of Marine Materials and Related Technologies, Zhejiang Key Laboratory of Marine Materials and Protective Technologies, Ningbo Institute of Materials Technology and Engineering, Chinese Academy of Sciences, Ningbo, 315201, China. myang@nimte.ac.cn.

PMID: 30607598
DOI: 10.1007/s00604-018-3108-8

Manganese-doped zinc oxide hollow balls for chemiresistive sensing of acetone vapors

Dongting Wang et al. Mikrochim Acta. 2019.

. 2019 Jan 3;186(1):44.

doi: 10.1007/s00604-018-3108-8.

Authors

Dongting Wang^{1

2}, Wenan Shang^{1

2}, Bingxue Zhang^{1

2}, Chunjie Jiang³, Fengdong Qu⁴, Minghui Yang⁵

Affiliations

¹ School of Chemistry and Chemical Engineering, Liaoning Normal University, Dalian, 116029, People's Republic of China.
² Key Laboratory of Marine Materials and Related Technologies, Zhejiang Key Laboratory of Marine Materials and Protective Technologies, Ningbo Institute of Materials Technology and Engineering, Chinese Academy of Sciences, Ningbo, 315201, China.
³ School of Chemistry and Chemical Engineering, Liaoning Normal University, Dalian, 116029, People's Republic of China. jiangcj@lnnu.edu.cn.
⁴ Key Laboratory of Marine Materials and Related Technologies, Zhejiang Key Laboratory of Marine Materials and Protective Technologies, Ningbo Institute of Materials Technology and Engineering, Chinese Academy of Sciences, Ningbo, 315201, China. fqu@nimte.ac.cn.
⁵ Key Laboratory of Marine Materials and Related Technologies, Zhejiang Key Laboratory of Marine Materials and Protective Technologies, Ningbo Institute of Materials Technology and Engineering, Chinese Academy of Sciences, Ningbo, 315201, China. myang@nimte.ac.cn.

PMID: 30607598
DOI: 10.1007/s00604-018-3108-8

Abstract

Both pure and Mn(II)-doped ZnO hollow structures were synthesized by a solvothermal reaction, and their phase structures, morphologies and elemental composition were characterized. SEM and TEM observations show the pure ZnO and the Mn(II)-doped ZnO balls to possess similar hollow structure with a particle size of about 1.5 μm. Their sensing properties were investigated, and the composite containing 1 atom% of Mn(II) (1% Mn-ZnO) is found be display the highest selectivity for acetone. The detection limit is 100 ppm acetone at 234 °C which is 4.6 times lower than that of the pure ZnO. In addition, the response time is shorter. Graphical abstract ZnO and Mn-doped ZnO hollow balls were prepared by a hydrothermal method, and their gas-sensing properties were investigated. Zinc(II) oxide doped with 1 atom% Mn(II) demonstrated an outstanding sensing behavior towards acetone vapors.

Keywords: Acetone vapors; Gas sensor; Hollow balls; Mn-doped ZnO; ZnO.

PubMed Disclaimer

Cited by

Three-Dimensional-Printed Photocatalytic Sponges Decorated with Mn-Doped ZnO Nanoparticles.
Vrithias NR, Katsara K, Papoutsakis L, Papadakis VM, Viskadourakis Z, Remediakis IN, Kenanakis G. Vrithias NR, et al. Materials (Basel). 2023 Aug 18;16(16):5672. doi: 10.3390/ma16165672. Materials (Basel). 2023. PMID: 37629963 Free PMC article.
Enhanced resistive acetone sensing by using hollow spherical composites prepared from MoO₃ and In₂O₃.
Jiang W, Meng L, Zhang S, Chuai X, Sun P, Liu F, Yan X, Gao Y, Liang X, Lu G. Jiang W, et al. Mikrochim Acta. 2019 May 16;186(6):359. doi: 10.1007/s00604-019-3471-0. Mikrochim Acta. 2019. PMID: 31098848
Mn-Modified ZnO Nanoflakes for Optimal Photoelectrochemical Performance Under Visible Light: Experimental Design and Theoretical Rationalization.
Das A, Liu D, Wary RR, Vasenko AS, Prezhdo OV, Nair RG. Das A, et al. J Phys Chem Lett. 2023 Nov 2;14(43):9604-9611. doi: 10.1021/acs.jpclett.3c02730. Epub 2023 Oct 20. J Phys Chem Lett. 2023. PMID: 37862673 Free PMC article.
Modification of photocatalytic activity and antibacterial properties of Mn₂O₃ by Zn ions doping.
Nasr RA, El-Sayed AF, El Komy GM, El-Bassyouni GT, Mousa SM. Nasr RA, et al. Sci Rep. 2025 Apr 24;15(1):14325. doi: 10.1038/s41598-025-95769-2. Sci Rep. 2025. PMID: 40274836 Free PMC article.

References

1. Mass Spectrom Rev. 2011 Mar-Apr;30(2):236-67 - PubMed
1. Analyst. 2011 May 21;136(10):2009-32 - PubMed
1. ACS Appl Mater Interfaces. 2014 Mar 26;6(6):3879-87 - PubMed
1. Nanoscale. 2015 Aug 7;7(29):12460-73 - PubMed
1. Cell Metab. 2017 Feb 7;25(2):262-284 - PubMed

Publication types

Actions

Save citation to file

Email citation

Add to Collections

Add to My Bibliography

Your saved search

Create a file for external citation management software

Your RSS Feed

Manganese-doped zinc oxide hollow balls for chemiresistive sensing of acetone vapors

Affiliations

Manganese-doped zinc oxide hollow balls for chemiresistive sensing of acetone vapors

Authors

Affiliations

Abstract

Similar articles

Cited by

References

Publication types

Grants and funding