Mg-Mg-bonded compounds with N,N'-dipp-substituted phenanthrene-diamido and o-phenylene-diamino ligands
- PMID: 30681693
- DOI: 10.1039/c9dt00028c
Mg-Mg-bonded compounds with N,N'-dipp-substituted phenanthrene-diamido and o-phenylene-diamino ligands
Abstract
Two Mg-Mg-bonded compounds were synthesized by using the ligands N,N'-bis(dipp)-phenanthrene-9,10-diimine (L2) and N,N'-bis(dipp)-o-phenylenediamine (H2L3; dipp = 2,6-diisopropylphenyl). These new Mg(i) species were characterized by X-ray diffraction, NMR, UV-Vis and fluorescence spectroscopy, and DFT computations. Their reactions with unsaturated organic molecules were examined.
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