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. 2019 Feb 12;55(14):2054-2057.
doi: 10.1039/c8cc09839e.

Terminal hydridozinc cation

Raju Chambenahalli  1 , Alex P Andrews, Florian Ritter, Jun Okuda, Ajay Venugopal
Affiliations

Terminal hydridozinc cation

Raju Chambenahalli et al. Chem Commun (Camb). .

Abstract

A thermally stable terminal hydridozinc cation has been isolated. The nucleophilicity of the hydride ligand is demonstrated by inserting carbon dioxide, carbodiimide and benzophenone across the Zn-H bond in a facile manner. Preliminary studies on catalytic hydrosilylation using PhSiH3 indicate that the hydridozinc cation in the presence of BPh3 can selectively reduce CO2 to PhSi(OCHO)3.

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