Regional Estimates of Chemical Composition of Fine Particulate Matter Using a Combined Geoscience-Statistical Method with Information from Satellites, Models, and Monitors

Abstract

An accurate fine-resolution surface of the chemical composition of fine particulate matter (PM_2.5) would offer valuable information for epidemiological studies and health impact assessments. We develop geoscience-derived estimates of PM_2.5 composition from a chemical transport model (GEOS-Chem) and satellite observations of aerosol optical depth, and statistically fuse these estimates with ground-based observations using a geographically weighted regression over North America to produce a spatially complete representation of sulfate, nitrate, ammonium, black carbon, organic matter, mineral dust, and sea-salt over 2000-2016. Significant long-term agreement is found with cross-validation sites over North America (R² = 0.57-0.96), with the strongest agreement for sulfate (R² = 0.96), nitrate (R² = 0.90), and ammonium (R² = 0.86). We find that North American decreases in population-weighted fine particulate matter (PM_2.5) concentrations since 2000 have been most heavily influenced by regional changes in sulfate and organic matter. Regionally, the relative importance of several chemical components are found to change with PM_2.5 concentration, such as higher PM_2.5 concentrations having a larger proportion of nitrate and a smaller proportion of sulfate. This data set offers information for research into the health effects of PM_2.5 chemical components.