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. 2019 Feb 19;55(16):2380-2383.
doi: 10.1039/c8cc08884e.

Halogen bonding effects on the outcome of reactions at metal centres

Lucas Carreras  1 , Jordi Benet-Buchholz, Antonio Franconetti, Antonio Frontera, Piet W N M van Leeuwen, Anton Vidal-Ferran
Affiliations

Halogen bonding effects on the outcome of reactions at metal centres

Lucas Carreras et al. Chem Commun (Camb). .

Abstract

Key findings regarding the effects of ligand preorganisation via halogen bonding on the outcome of reactions at rhodium are reported. An unprecedented halogen bonding-mediated oxidative addition of CAr-I bonds to rhodium with efficient formation of cyclometallated species deserves special mention.

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