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. 2019 Apr 19;84(8):4940-4947.
doi: 10.1021/acs.joc.9b00106. Epub 2019 Mar 18.

Ir-Catalyzed C-H Amidation and Borylation of Anthraquinones

Andrew M Camelio  1 , Robert J Wright  2 , Nicole T Knight  2 , Brian A Jazdzewski  2
Affiliations

Ir-Catalyzed C-H Amidation and Borylation of Anthraquinones

Andrew M Camelio et al. J Org Chem. .

Abstract

A mild, regioselective, iridium-catalyzed C-H amidation and borylation of anthraquinones to the o-sulfonamide and m-borylated products has been developed. The anthraquinone carbonyl moieties direct the C-H amidation with high selectivity to afford the ortho-substituted products in modest to high yields.

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