Polymeric graphitic carbon nitride (g-C3N4)-based semiconducting nanostructured materials: Synthesis methods, properties and photocatalytic applications

Abstract

In recent years, various facile and low-cost methods have been developed for the synthesis of advanced nanostructured photocatalytic materials. These catalysts are required to mitigate the energy crisis, environmental deterioration, including water and air pollution. Among the various semiconductors explored, recently novel classes of polymeric graphitic carbon nitride (g-C₃N₄)-based heterogeneous photocatalysts have established much greater importance because of their unique physiochemical properties, large surface area, low price, and long service life, ease of synthesis, product scalability, controllable band gap properties, low toxicity, and high photocatalytic activity. The present comprehensive review focuses on recent achievements in a number of facile chemical synthesis methods for semiconducting polymeric carbon nitrides and their heterogeneous nanohybrids with various dopants, nanostructured metals, metal oxides, and nanocarbons, as well as the parameters influencing their physiochemical properties and photocatalytic efficiency, which are discussed with reference to various catalytic applications such as air (NO_x) purification, wastewater treatment, hydrogen generation, CO₂ reduction, and chemical transformation. The mechanisms for the superior photocatalytic activity of polymeric g-C₃N₄-based heterogeneous photocatalysts are also discussed. Finally, the challenges, prospects, and future directions for photocatalytic polymeric g-C₃N₄-based semiconducting materials are described.

Keywords: Bandgap engineering; CO(2) reduction; Carbon nitride (C(3)N(4)); Chemical transformation; Heterogeneous hybrid nanostructures; Hydrogen production; Photocatalysis; Treatment of air and water pollution.