Multifunctional graphene oxide loaded nanofibrous membrane for removal of dyes and coliform from water

Abstract

In this study, we fabricated a trifunctional polyurethane (PU)/graphene oxide (GO) electrospun membrane for adsorption of organic dyes such as methylene blue (MB) and rhodamine B (RB). Moreover, the prepared membrane showed antifouling property and inhibition against bacteria. The GO modified PU nanofiber shows a maximum adsorption capacity of 109.88 mg/g and 77.15 mg/g towards MB and RB respectively. Theoretical studies confirmed that the dye adsorption is followed pseudo-second-order kinetics and the Langmuir adsorption isotherm. The superhydrophilic PU/10GO membrane exhibits high water flux of 17,706 lm^-2hr^-1. This membrane also exhibits good antifouling property for separating oil-in-water emulsions with 99.99% separation efficiency. The Mechanism of antifouling was investigated using Hermia model. The results showed that PU/GO membranes also have antibacterial activity against Gram-negative and Gram-positive bacterias. Thus a superhydrophilic nanofibrous antifouling membrane that can reject both organic dye molecule and bacteria from contaminated water is developed using simple electrospinning technique.

Keywords: Antifouling; Dye adsorption; Graphene oxide; Langmuir model; Polyurethane; Superhydrophilicity.