Improvement of mechanical properties of Y-TZP by thermal annealing with monoclinic zirconia nanoparticle coating

Abstract

Objective: To assess whether a thermal annealing with a monoclinic zirconia (mZrO₂) nanoparticle coating can improve the reliability of sandblasted yttria-stabilized tetragonal zirconia polycrystals (Y-TZP) and maintain its mechanical strength.

Methods: Commercially available Y-TZP (Lava Frame, 3M Dental Products) disks were sintered and surface-treated as follows: AS (as sintered, with no treatment); SB (sandblasting); SB-TA (sandblasting followed by thermal annealing at 1000 °C); and SB-mZr-TA (sandblasting followed by thermal annealing at 1000 °C with the mZrO₂ nanoparticle coating). The mZrO₂ nanoparticles of 21 nm in size were prepared by a hydrothermal method, and coated onto Y-TZP sintered disks as a 5 g/L ethanol dispersion. Biaxial flexural strength (S) was measured using the piston-on-three-ball test, and reliability was evaluated by the Weibull modulus (m).

Results: Biaxial flexural tests showed a significant increase in the strength of Group SB (S_SB = 1445 ± 191 MPa) compared with Group AS (S_AS = 1071 ± 112 MPa). The thermal annealing improved the reliabilities of the sandblasted Y-TZP (m_SB-TA = 20.14 and m_SB-mZr-TA = 21.33), as compared with Group SB (m_SB = 7.77). However, the conventional thermal annealing without the mZrO₂ coating caused a significant decrease in the strength of sandblasted Y-TZP (S_SB-TA = 1273 ± 65 MPa). Importantly, the mZrO₂ coating prevented the decrease in the strength caused by conventional thermal annealing (S_SB-mZr-TA = 1379 ± 65 MPa).

Significance: The thermal annealing with the mZrO₂ nanoparticle coating can improve the reliability of sandblasted Y-TZP and maintain its mechanical strength, which would otherwise be decreased by the conventional annealing process.

Keywords: Biaxial flexural strength; Monoclinic phase; Thermal annealing; Yttria-stabilized tetragonal zirconia polycrystals.