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. 2016:93:228-244.
doi: 10.15227/orgsyn.093.0228. Epub 2016 Jul 21.

Oxyboration: Synthesis of Borylated Benzofurans

Darius J Faizi  1 , Nicole A Nava  1 , Mohammad Al-Amin  1 , Suzanne A Blum  1
Affiliations

Oxyboration: Synthesis of Borylated Benzofurans

Darius J Faizi et al. Organic Synth. 2016.

Abstract

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Figures

Figure 1
Figure 1
Step A - Color before and after addition of 2
Figure 2
Figure 2
Step B - Part a - Reaction mixture during addition of 3
Figure 3
Figure 3
Step B - Part c - Reaction mixture heated to 60 °C
Scheme 1
Scheme 1
The Proposed Mechanism for the Oxyboration Reaction
See this image and copyright information in PMC

References

    1. Department of Chemistry, University of California, Irvine, Irvine, CA 92617. <email>blums@uci.edu</email>. We thank the NIH (1R01GM098512-01) for support.

    1. Hoye TR, Aspaas AW, Eklov BM, Ryba TD. Org Lett. 2005;7:2205–2208. - PubMed
    1. Hurd DT. J Am Chem Soc. 1948;70:2053–2055.
    1. Brown HC. Tetrahedron. 1961;12:117–138.
    1. Suginome M, Yamamoto A, Murakami M. J Am Chem Soc. 2003;125:6358–6359. - PubMed
    2. Suginome M. Chem Rec. 2010;10:348–358. - PubMed
    3. Suginome M, Nakamura H, Ito Y. Chem Commun. 1996:2777–2778.
    4. Ishiyama T, Nishijima K, Miyaura N, Suzuki A. J Am Chem Soc. 1993;115:7219–7225.
    5. Marder TB, Norman NC. Top Catal. 1998;5:63–73.
    6. Lappert MF, Prokai B. J Orgmet Chem. 1964;1:384–400.
    7. Hara S, Dojo H, Takinami S, Suzuki A. Tetrahedron Lett. 1983;24:731–734.

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