Low-cost powder metallurgy Ti-Cu alloys as a potential antibacterial material

Abstract

Ti and Ti alloys are extensively used in biomedical applications due to their excellent biocompatibility and mechanical properties but their high-cost of production is still a limiting factor. It has been reported that the addition of Cu to Ti enables the creation of Ti alloys exhibiting antibacterial properties. Therefore, in this study Ti-Cu alloys (Cu = 0.5, 2.5 and 5 in wt.%) with potential antibacterial activity were fabricated by powder metallurgy (i.e. cold press and vacuum sintering) to reduce the production costs. As many biomaterials are employed as structural components, the Ti-Cu alloys were also subjected to β forging in order to improve their mechanical properties. It is found that the studied Ti-Cu alloys have superior mechanical properties to other commonly used Ti-based materials and are, thus, potential candidate for biomedical applications. Moreover, among the tested materials, the β forged Ti-5Cu alloys has tensile strength of 904 MPa, elongation of 6.7%, and Vickers hardness of 302 HV, which are comparable to those of the Ti-6Al-4V, and comprises the Ti₂Cu phase (confirmed by the XRD) as microstructural feature, which is fundamental to guarantee antibacterial properties.

Keywords: Forging; Homogeneous microstructure; Powder metallurgy; Ti-Cu; Titanium alloys; β alloy.