Elimination performance of methylene blue, methyl violet, and Nile blue from aqueous media using AC/CoFe2O4 as a recyclable magnetic composite

Abstract

The present paper describes the sono-assisted adsorption (sono-adsorption) of methylene blue (MB), methyl violet (MV), and Nile blue (NB) from aqueous solution by AC/CoFe₂O₄ magnetic composite. FT-IR, TGA-DTG, VSM, XRD, TEM, SEM, EDX, Map, and Raman analysis were used to characterize the magnetic composite. The magnetization saturation value of AC/CoFe₂O₄ magnetic composite was determined to be 53.06 emu/g. Dye sono-adsorption efficiency was increased by increasing adsorbent dose, pH value, and contact time, but not dye concentration. Pseudo-first-order, pseudo-second-order, and intra-particle diffusion models were used to study the kinetic behavior of the cationic dye sono-adsorption. The sono-adsorption kinetics was reasonably followed by pseudo-second-order model (R² > 0.998). The results showed that the Freundlich model (R² > 0.976) was more able to describe the sono-adsorption equilibrium behavior than Langmuir, D-R, and Scatchard models. The maximum sono-adsorption capacity of NB, MV, and MB was determined as 86.24, 83.90, and 87.48 mg/g, respectively. Based on the parameters derived from isotherm modeling (R_L, n, and E), the sono-adsorption process of cationic dyes is desirable and physical. An increase in NaCl concentration reduced the sono-adsorption efficiency for all dyes. Also, the adsorption-desorption of AC/CoFe₂O₄ magnetic was studied up to 10 stages, and it was confirmed that the sono-adsorption efficiency is acceptable up to the eight stage. AC/CoFe₂O₄ magnetic composite is, therefore, an affordable and recyclable adsorbent to remove the molecule of NB, MV, and MB dyes from aqueous media.

Keywords: Activated carbon/cobalt ferrite; Aqueous media; Cationic dye; Sono-adsorption; Ultrasonic.