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. 2019 Jun 25;55(50):7195-7198.
doi: 10.1039/c9cc02273b. Epub 2019 Jun 5.

A ruthenium porphyrin-based porous organic polymer for the hydrosilylative reduction of CO2 to formate

Grace M Eder  1 , David A Pyles  1 , Eric R Wolfson  1 , Psaras L McGrier  1
Affiliations

A ruthenium porphyrin-based porous organic polymer for the hydrosilylative reduction of CO2 to formate

Grace M Eder et al. Chem Commun (Camb). .

Abstract

A ruthenium porphyrin-based porous organic polymer (POP) was synthesized, characterized, and used to reduce CO2 to a formate salt. We demonstrate that Ru-BBT-POP can be utilized to reduce CO2 to a silyl formate and then converted to potassium formate with a respectable turnover number and frequency.

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