MXenes for Plasmonic Photodetection

Abstract

MXenes have recently shown impressive optical and plasmonic properties associated with their ultrathin-atomic-layer structure. However, their potential use in photonic and plasmonic devices has been only marginally explored. Photodetectors made of five different MXenes are fabricated, among which molybdenum carbide MXene (Mo₂ CT_x ) exhibits the best performance. Mo₂ CT_x MXene thin films deposited on paper substrates exhibit broad photoresponse in the range of 400-800 nm with high responsivity (up to 9 A W^-1 ), detectivity (≈5 × 10¹¹ Jones), and reliable photoswitching characteristics at a wavelength of 660 nm. Spatially resolved electron energy-loss spectroscopy and ultrafast femtosecond transient absorption spectroscopy of the MXene nanosheets reveal that the photoresponse of Mo₂ CT_x is strongly dependent on its surface plasmon-assisted hot carriers. Additionally, Mo₂ CT_x thin-film devices are shown to be relatively stable under ambient conditions, continuous illumination and mechanical stresses, illustrating their durable photodetection operation in the visible spectral range. Micro-Raman spectroscopy conducted on bare Mo₂ CT_x film and on gold electrodes allowing for surface-enhanced Raman scattering demonstrates surface chemistry and a specific low-frequency band that is related to the vibrational modes of the single nanosheets. The specific ability to detect and excite individual surface plasmon modes provides a viable platform for various MXene-based optoelectronic applications.

Keywords: MXenes; flexible photodetectors; low-frequency Raman spectroscopy; molybdenum carbide; surface plasmons.