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. 2019 Jul 5;21(13):5006-5009.
doi: 10.1021/acs.orglett.9b01549. Epub 2019 Jun 25.

Synthesis of 4-Deoxy Pyranosides via Catalyst-Controlled Site-Selective Toluoylation of Abundant Sugars

Masanori Yanagi  1 , Yoshihiro Ueda  1 , Ryo Ninomiya  1 , Ayumi Imayoshi  1 , Takumi Furuta  1 , Kenji Mishiro  1 , Takeo Kawabata  1
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Synthesis of 4-Deoxy Pyranosides via Catalyst-Controlled Site-Selective Toluoylation of Abundant Sugars

Masanori Yanagi et al. Org Lett. .

Abstract

A two-step procedure was developed for the synthesis of 4-deoxy pyranosides from the parent pyranosides with four hydroxy groups via organocatalytic site-selective acylation and reductive deacyloxylation.

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