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. 2019 Jul 24;119(14):8846-8953.
doi: 10.1021/acs.chemrev.9b00033. Epub 2019 Jul 11.

Enantioenriched Helicenes and Helicenoids Containing Main-Group Elements (B, Si, N, P)

Kais Dhbaibi  1   2 , Ludovic Favereau  1 , Jeanne Crassous  1
Affiliations
Free article

Enantioenriched Helicenes and Helicenoids Containing Main-Group Elements (B, Si, N, P)

Kais Dhbaibi et al. Chem Rev. .
Free article

Abstract

In this review, we discuss the rich chemistry of helicenes and helicenoids containing main-group elements. Enantioenriched helicenic derivatives containing main-group elements B, Si, N, and P, either incorporated within the helical backbone or grafted to it, will be thoroughly presented. We will describe their synthesis, resolution, and asymmetric synthesis, their structural features, electronic and chiroptical properties, and emission, together with other photochemical properties and applications.

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