Controlling micropollutants in tertiary municipal wastewater by O3/H2O2, granular biofiltration and UV254/H2O2 for potable reuse applications

Abstract

A comprehensive pilot study was carried out to experimentally assess the potential of newly developed treatment trains integrating two-stage AOPs and biofiltration to reach potable reuse water quality standards from municipal wastewater. The processes consisted of a two-stage AOPs with (carbon or limestone) biofiltration, the first AOP (O₃/H₂O₂) serving as pre-treatment to biofiltration and the second AOP (UV₂₅₄/H₂O₂) serving as post-biofiltration finishing step to ensure advanced disinfection. A comprehensive monitoring campaign was put in place resulting from the combination of targeted, non-targeted and suspect screening measurements. It was found that 13 organic micropollutants were detected from a list of 219 suspects although at ng/L level only. For the treatment conditions piloted in this study (O₃ = 13 ± 0.5 mg/L, H₂O₂ = 11 ± 0.4 mg/L for the O₃/H₂O₂ process, and UV = 410 ± 63.5 mJ/cm², H₂O₂ = 5 mg/l for the UV₂₅₄/H₂O₂ process), it was possible to estimate the overall removal efficacy for each unit process, which was found to follow this order: RO (99%) > BAC (87%) > O₃-H₂O₂ (78%) > BAL (67%) > UV/H₂O₂ (43%) > AOP contact chamber (19%) > UF(0%), with the treatment train integrating two AOPs and granular biofiltration with activated carbon (O₃/H₂O₂ + BAC + UV₂₅₄/H₂O₂) showing superior performance with a 99% abatement in total micropollutants. No ecotoxicologically-positive response was generally observed for any of the effluent samples from the tested trains, even when pre-concentration factors up to 100-1000 times were employed to increase the sensitivity of the bioassay methods.

Keywords: Advanced oxidation processes; Biofiltration; Micropollutants; Potable reuse; Wastewater.