Skip to main page content
U.S. flag

An official website of the United States government

Dot gov

The .gov means it’s official.
Federal government websites often end in .gov or .mil. Before sharing sensitive information, make sure you’re on a federal government site.

Https

The site is secure.
The https:// ensures that you are connecting to the official website and that any information you provide is encrypted and transmitted securely.

Access keys NCBI Homepage MyNCBI Homepage Main Content Main Navigation
. 2019 Oct 14;48(40):14979-14983.
doi: 10.1039/c9dt03402a.

Brightly phosphorescent tetranuclear copper(i) pyrazolates

H V Rasika Dias  1 , Himashinie V K Diyabalanage, Mukunda M Ghimire, Joshua M Hudson, Devaborniny Parasar, Chammi S Palehepitiya Gamage, Shan Li, Mohammad A Omary
Affiliations

Brightly phosphorescent tetranuclear copper(i) pyrazolates

H V Rasika Dias et al. Dalton Trans. .

Abstract

Described herein is the synthesis and photophysics of two tetranuclear copper complexes, {[3,5-(Pri)2,4-(Br)Pz]Cu}4 and {[3-(CF3),5-(But)Pz]Cu}4 tailor-designed by manipulating the pyrazolyl ring substituents. Unlike their trinuclear analogues, the luminescence of the tetranuclear species is molecular (not supramolecular) in nature with extremely high solid-state quantum yields of ∼80% at room temperature.

PubMed Disclaimer

LinkOut - more resources