Solid-State Conversion Synthesis of Advanced Electrocatalysts for Water Splitting

Abstract

Electrolytic water technology is promising for sustainable energy utilization, but the lack of efficient electrocatalysts retards its application. The intrinsic activity of electrocatalysts is determined by its electronic structure, whereas the apparent activity can be further optimized by reasonable design on micro-/nanostructures of electrocatalysts. The core goal of electrocatalytic research is to reveal the relationship between the structure and performance of electrocatalysts, which is also the basis of reasonable design and construction of efficient electrocatalysts. Traditional synthetic methods, namely bottom-up and top-down routes, usually induce the change of different structural parameters at the same time. The solid-state conversion strategy, which is converts solid precursors into target materials through chemical reactions, has been widely adopted to produce materials with precisely controllable structures. In this Minireview, we focus on recent advances in the solid-state conversion synthesis of water-splitting electrocatalysts. First, the basis of solid-state conversion chemistry is introduced. Then, the specific methods of precise control of electronic structure by solid-state conversion and the relationship between electronic structure and performance are summarized. Based on the understanding of the electronic structure-performance relationship, synergistic regulation of electronic structure and micro-/nanostructures by solid-state conversion to achieve the copromotion of intrinsic activity and apparent activity are described. Finally, the remaining challenges in this field are discussed, and future research directions are proposed as well.

Keywords: electrocatalysis; electronic structure; solid-state conversion synthesis; synergistic manipulation; water splitting.