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. 2019 Dec 1:486:107855.
doi: 10.1016/j.carres.2019.107855. Epub 2019 Oct 25.

A practical approach to Dideoxy-1,4- and 1,5-iminopentitols from protected sugar hemiacetals

Justyna Jaszczyk  1 , Sizhe Li  1 , Chloé Cocaud  1 , Cyril Nicolas  2 , Olivier R Martin  3
Affiliations

A practical approach to Dideoxy-1,4- and 1,5-iminopentitols from protected sugar hemiacetals

Justyna Jaszczyk et al. Carbohydr Res. .

Abstract

The convenient and straightforward preparation of dideoxy-1,4- and 1,5-iminopentitol derivatives from protected sugar hemiacetals by way of N-tert-butanesulfinyl glycosylamines and open-chain aminoalditols is reported. The synthetic procedure is a method of choice for the making of these important scaffolds of biological interest.

Keywords: Aminoalditols; Dideoxyiminopentitols; N-tert-butanesulfinyl glycosylamines; Sugar hemiacetals.

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