Green-Light Activatable, Water-Soluble Red-Shifted Coumarin Photocages
- PMID: 31714093
- DOI: 10.1021/acs.orglett.9b03624
Green-Light Activatable, Water-Soluble Red-Shifted Coumarin Photocages
Abstract
Easily accessible green-light activatable (>500 nm) photocages based on red-shifted, π-extended coumarin scaffolds are developed with uncaging efficiencies similar to those of recently introduced BODIPY derivatives. The photocages possess increased aqueous solubility, high absorption coefficients within the 450-600 nm range, and exceptionally high two-photon cross sections.
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