The effect of different denitrification and partial nitrification-Anammox coupling forms on nitrogen removal from mature landfill leachate at the pilot-scale

Abstract

The effects on nitrogen removal from landfill leachate were compared between the denitrification (DN) direct coupling in Partial nitrification (PN)-Anammox (DN+(PN-Anammox)) and pre-DN followed by PN-Anammox (DN-PN-Anammox). Both processes can achieve coupling and high nitrogen removal. However, the DN+(PN-Anammox) process was not conducive to the treatment of high-COD wastewater. The total nitrogen removal rate (TNRR) and total nitrogen removal efficiency (TNRE) were stable at 0.31 kg/(m³·d) and 76.3%. When UASB was added to denitrification and transform the process into DN-PN-Anammox, the influent NH₄⁺-N and COD concentrations were increased to 2230 and 2612 mg/L, TNRR and TNRE reached 0.45 kg/(m³·d) and 96.7%, respectively. The DN-PN-Anammox process not only was able to make full use of degradable COD in wastewater to realize the NO₃^--N removal, but also benefited the growth of autotrophic bacteria. The DN-PN-Anammox reduced the oxygen supply and was more conducive to the treatment of highly-concentrated mature landfill leachate.

Keywords: Coupling form; Landfill leachate; Nitrogen removal; PN-Anammox; Pilot-scale.