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. 2020 Feb 3;59(6):2251-2255.
doi: 10.1002/anie.201911965. Epub 2019 Dec 27.

Separation of Bromoalkanes Isomers by Nonporous Adaptive Crystals of Leaning Pillar[6]arene

Affiliations

Separation of Bromoalkanes Isomers by Nonporous Adaptive Crystals of Leaning Pillar[6]arene

Jia-Rui Wu et al. Angew Chem Int Ed Engl. .

Abstract

Haloalkanes are important chemicals in synthetic chemistry and petrochemical industry, but the separation of their isomers is a big hurdle. Herein, we report a facile energy-efficient adsorptive separation strategy using a new class of nonporous adaptive crystals based on leaning pillar[6]arene. Desolvated perethylated leaning pillar[6]arene crystals (EtLP6) with interesting nonporous character show a preference for 1-bromoalkane isomers over 2-bromoalkane isomers. EtLP6 is capable of separating 1-bromopropane, 1-bromobutane, and 1-bromopentane from the corresponding 1:1 (v/v) mixtures of 1/2-positional isomers with purities from 89.6 % to 96.3 % in only one adsorption cycle. The selectivity is endowed by the different host-guest binding modes and different stabilities of EtLP6 crystalloids loaded with 1- and 2-positional isomers. Significantly, the guest-adsorbed assemblies are highly stable at room temperature and EtLP6 can be reused many times without any decrease in performance.

Keywords: host-guest systems; isomers separation; leaning pillar[6]arene; nonporous adaptive crystals; supramolecular chemistry.

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References

    1. None
    1. P. Comba, S. Wunderlich, Chem. Eur. J. 2010, 16, 7293-7299;
    1. L. Vasáros, H. J. Machulla, W. Tornau, J. Chromatogr. A 1971, 62, 458-461;
    1. K. Jie, Y. Zhou, E. Li, R. Zhao, M. Liu, F. Huang, J. Am. Chem. Soc. 2018, 140, 3190-3193.
    1. M. Hartmann, S. Kunz, D. Himsl, O. Tangermann, S. Ernst, A. Wagener, Langmuir 2008, 24, 8634-8642.

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