A continuous-flow combined process based on partial nitrification-Anammox and partial denitrification-Anammox (PN/A + PD/A) for enhanced nitrogen removal from mature landfill leachate

Abstract

A novel continuous-flow combined process of partial nitrification, Anammox (PN/A) and partial denitrification-Anammox (PD/A) was established to achieve enhanced nitrogen removal from landfill leachate. The NH₄⁺-N transformation rate and NO₂^--N accumulation rate in the PN reactor reached 93.4% and 91.5%, respectively. The nitrite generated from the PN reactor was combined with influent (38%) and fed into the Anammox reactor. The nitrate produced in the Anammox reactor was then discharged to PD/A reactor, where nitrate was transformed to nitrite and removed via Anammox. Under a COD/NO₃^--N ratio of 4.0, the NO₃^--N-to-NO₂^--N transformation ratio (NTR) and Anammox contribution rate reached 60.4% and 57.1% in PD/A reactor. The final effluent TN concentration was 15.7 mg/L, and the efficiency of TN removal could reach 98.8%. By combining PN/A with PD/A, enhanced nitrogen removal from landfill leachate was achieved successfully with an external carbon source addition (COD/NH₄⁺-N) of 0.28.

Keywords: Anammox; Enhanced nitrogen removal; Landfill leachate; Partial denitrification; Partial nitrification.