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. 2020 Mar 9;59(11):4370-4374.
doi: 10.1002/anie.201916279. Epub 2020 Feb 3.

Site-Selective 1,2-Dicarbofunctionalization of Vinyl Boronates through Dual Catalysis

Shang-Zheng Sun  1   2 , Yaya Duan  1 , Riccardo S Mega  1 , Rosie J Somerville  1   2 , Ruben Martin  1   3
Affiliations

Site-Selective 1,2-Dicarbofunctionalization of Vinyl Boronates through Dual Catalysis

Shang-Zheng Sun et al. Angew Chem Int Ed Engl. .

Abstract

A modular, site-selective 1,2-dicarbofunctionalization of vinyl boronates with organic halides through dual catalysis is described. This reaction proceeds under mild conditions and is characterized by excellent chemo- and regioselectivity. It thus represents a complementary new technique for preparing densely functionalized alkyl boron architectures from simple and accessible precursors.

Keywords: Ni; dicarbofunctionalization; dual catalysis; homogeneous catalysis; radical reactions.

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References

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