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. 2020 Apr 3;85(7):4785-4794.
doi: 10.1021/acs.joc.0c00010. Epub 2020 Mar 18.

Cp*Co(III)-Catalyzed C-7 C-C Coupling of Indolines with Aziridines: Merging C-H Activation and Ring Opening

Pinaki Bhusan De  1 , Sayan Atta  1 , Sourav Pradhan  1 , Sonbidya Banerjee  1 , Tariq A Shah  1 , Tharmalingam Punniyamurthy  1
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Cp*Co(III)-Catalyzed C-7 C-C Coupling of Indolines with Aziridines: Merging C-H Activation and Ring Opening

Pinaki Bhusan De et al. J Org Chem. .

Abstract

A Cp*Co(III)-catalyzed directing group-assisted C7 C-C coupling of indolines with aziridines has been developed by merging C-H activation and ring opening. The use of cobalt catalyst, detection of a Co(III) intermediate, and late-stage removal of the directing group are important practical features.

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