Recent developments in the application of kraft pulping alkaline chemicals for lignocellulosic pretreatment: Potential beneficiation of green liquor dregs waste

Abstract

Lignocellulosic waste has offered a cost-effective and food security-wise substrate for the generation of biofuels and value-added products. However, its recalcitrant properties necessitate pretreatment. Of the various pretreatment methods, alkaline techniques have gained prominence as efficient catalysts. The kraft pulping industry represents a major hub for the generation of white, black and green liquor alkaline solutions during the paper making process. Despite its well-known significance in the kraft pulping process, green liquor (GL) has been widely applied for lignocellulosic pretreatment. Recently, green liquor dregs (GLD), an alkaline waste generated from the kraft pulping industry has piqued interest. Therefore, this review outlines the general flow of the kraft pulping process and the alkaline chemicals derived. In addition, the extensively studied GL for lignocellulosic pretreatment is discussed. Subsequently, the potential beneficiation of GLD for lignocellulosic pretreatment is presented. Furthermore, the challenges and prospects of lignocellulosic pretreatments are highlighted.

Keywords: Biofuels; Green liquor dregs; Kraft pulping; Lignocellulosic pretreatment; Value-added products.