Contamination features and ecological risks of heavy metals in the farmland along shoreline of Caohai plateau wetland, China

Abstract

Spatial distribution characteristics of heavy metal (Cd, Pb, Cr, Cu, Zn, and Hg) contents and their ecological risks in the farmland along the shoreline of the Caohai wetland were investigated. Incubation experiments were also conducted to characterize the emission of heavy metals across soil-water interface if the farmland was reclaimed to wetland. The results showed that spatial distribution characteristics of these heavy metal contents were significantly different. Concentrations of Cd, Zn, and Hg were higher than the corresponding geochemical background levels. Ecological risk assessment suggested that the farmland along the shoreline of Caohai wetland were characterized by non-pollution or slight pollution of Pb, Cr, and Cu, moderate pollution of Cd, slight to moderate pollution of Hg, and slight pollution of Zn. Emission rates of Cd, Zn, and Hg across soil/sediment-water interface first increased, then decreased and finally reached equilibrium after the farmland soil was submersed. The contribution-rates of Cd, Zn, and Hg transferring from sediment to overlying water were calculated to be 12.7%, 14.8%, and 10.4%, respectively. We conclude that environmental issues caused by heavy metals, especially by Cd, Zn, and Hg, in the farmland along the shoreline of the Caohai wetland should be paid great attention.

Keywords: Ecological risks; Emission characteristics; Fertilizers; Heavy metal; Spatial distribution characteristics; pH.