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. 2020 Jun 18;56(49):6672-6675.
doi: 10.1039/d0cc02506b.

Helicity of a polyacetylene directed by molecular recognition of biscalixarene and fullerene

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Helicity of a polyacetylene directed by molecular recognition of biscalixarene and fullerene

Takehiro Hirao et al. Chem Commun (Camb). .

Abstract

Chiral biscalixarenes and a C60-appended polyphenylacetylene have been synthesized. The chiral biscalixarene encapsulated the C60 unit of the phenylpolyacetylene, which induced the preferred helicity of the polyacetylene.

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