Synthesis of Acylboron Compounds
- PMID: 32510826
- DOI: 10.1002/anie.202005050
Synthesis of Acylboron Compounds
Abstract
Acylboron compounds are emerging as versatile functional groups with applications in multiple research fields. Their synthesis, however, is still challenging and requires innovative methods. This Minireview provides an overview on the obstacles of acylboron synthesis and highlights notable advances within the last three years on new strategies to overcome the challenges posed by the formation of acyl-boron bonds.
Keywords: acylboron; boron; carbonyl; synthesis design; synthetic methods.
© 2020 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.
References
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- First instance of acylsilanes: A. G. Brook, J. Am. Chem. Soc. 1957, 79, 4373-4375; selected reviews on acylsilanes:
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- H.-J. Zhang, D. L. Priebbenow, C. Bolm, Chem. Soc. Rev. 2013, 42, 8540-8571;
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- M. A. Brook, Silicon in Organic, Organometallic and Polymer Chemistry, Wiley, New York, 2000.
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