The enhanced photocatalytic performance of SnS2@MoS2 QDs with highly-efficient charge transfer and visible light utilization for selective reduction of mythlen-blue

Abstract

Molybdenum disulfide (MoS₂) has recently been considered as an effective material for potential photocatalytic applications; however, its photocatalytic activity was limited due to the low density of active sites. In this work, MoS₂ Quantum dots (QDs) were synthesized via the ultrasonication technique to construct heterostructure with SnS₂ nanosheets (SnS₂@MoS₂ QDs) and the prepared materials were tested for photocatalytic applications for Methylene blue (MB). Pristine SnS₂ and SnS₂@MoS₂ QDs nanocomposite were analyzed by XRD, TEM, PL, and Uv-Vis. Both SnS₂ and SnS₂@MoS₂ QDs exhibited a single trigonal phase with the P-3m1 space group. The TEM analysis confirmed the coupling between the pristine SnS₂ and SnS₂@MoS₂ QDs. The results of photocatalytic activity toward MB indicated that SnS₂@MoS₂ QDs material exhibits much superior photocatalytic performance compared to pristine SnS₂. The excellent photodegradation performance of SnS₂@MoS₂ QDs is due in the main to the formation of heterojunction between SnS₂ and MoS₂ QDs with narrow bandgap formation, which results in a facile carriers transfer and thus high photocatalytic efficiency. A representative mechanism of the photodegradation for SnS₂@MoS₂ QDs photocatalyst was proposed. Such an ultrasonic technique is capable of producing small metallic particle size that can be used to construct new heterostructures for water remediation applications.