Synthesis and characterization of magnetic clay-based carboxymethyl cellulose-acrylic acid hydrogel nanocomposite for methylene blue dye removal from aqueous solution

Abstract

Carboxymethyl cellulose/poly(acrylic acid) (CMC-cl-pAA) hydrogel and its magnetic hydrogel nanocomposite (CMC-cl-pAA/Fe₃O₄-C30B) were prepared via a free radical polymerization method and used as adsorbents for adsorption of methylene blue (MB) dye. The samples were characterized using Fourier transform infrared, X-ray diffraction, thermogravimetric analysis, scanning electron microscopy coupled with energy-dispersive X-ray spectrometer, high-resolution transmission electron microscope, and dynamic mechanical analysis. The adsorption performance of the prepared adsorbents was studied in a batch mode. Adsorption kinetics and isotherm models were applied in the experimental data to evaluate the nature as well as the mechanism of adsorption processes. It was deduced that the adsorption followed the pseudo-second-order rate equation and Langmuir isotherm models. The maximum adsorption capacities were found to be 1109.55 and 1081.60 mg/g for CMC-cl-pAA hydrogel and CMC-cl-pAA/Fe₃O₄-C30B hydrogel nanocomposite, respectively. The adsorption thermodynamic studies suggested that the adsorption process was spontaneous and endothermic for CMC-cl-pAA/Fe₃O₄-C30B hydrogel nanocomposite. The homogeneous dispersion of the Fe₃O₄-C30B nanocomposite in the CMC-cl-pAA hydrogel significantly improved the thermal stability, mechanical strength, and excellent regeneration stability. This study demonstrates the application potential of the fascinating properties of CMC-cl-pAA/Fe₃O₄-C30B hydrogel nanocomposite as a highly efficient adsorbent in the removal of organic dyes from aqueous solution.

Keywords: Adsorption behaviour; Carboxymethyl cellulose; Hydrogel nanocomposite; Methylene blue; Polymerization; Thermomechanical properties.