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Review
. 2021 Jan 7;27(2):491-511.
doi: 10.1002/chem.202003267. Epub 2020 Oct 19.

Emerging Organometallic Methods for the Synthesis of C-Branched (Hetero)aryl, Alkenyl, and Alkyl Glycosides: C-H Functionalization and Dual Photoredox Approaches

Juba Ghouilem  1 , Morgane de Robichon  2 , Franck Le Bideau  1 , Angélique Ferry  2 , Samir Messaoudi  1
Affiliations
Review

Emerging Organometallic Methods for the Synthesis of C-Branched (Hetero)aryl, Alkenyl, and Alkyl Glycosides: C-H Functionalization and Dual Photoredox Approaches

Juba Ghouilem et al. Chemistry. .

Abstract

Transition-metal-catalyzed C-H functionalization and photoredox nickel dual catalysis have emerged as innovative and powerful avenues for the synthesis of C-branched glycosides. These two concepts have been recently established and provide efficient and mild methods for accessing a series of valuable complex C-branched glycosides of great interest. Herein, recent developments in the synthesis of C-branched aryl/alkenyl/alkyl glycosides through these two approaches are highlighted.

Keywords: C−H functionalization; glycosylation; homogeneous catalysis; photochemistry; transition metals.

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