Skip to main page content
U.S. flag

An official website of the United States government

Dot gov

The .gov means it’s official.
Federal government websites often end in .gov or .mil. Before sharing sensitive information, make sure you’re on a federal government site.

Https

The site is secure.
The https:// ensures that you are connecting to the official website and that any information you provide is encrypted and transmitted securely.

Access keys NCBI Homepage MyNCBI Homepage Main Content Main Navigation
. 2020 Sep 29;56(77):11429-11432.
doi: 10.1039/d0cc04373g.

Copper-catalyzed (4+1) and (3+2) cyclizations of iodonium ylides with alkynes

Hao Liang  1 , Xiaobo He, Yaqi Zhang, Bin Chen, Jia-Sheng Ouyang, Yongsu Li, Bendu Pan, Chitreddy V Subba Reddy, Wesley Ting Kwok Chan, Liqin Qiu
Affiliations

Copper-catalyzed (4+1) and (3+2) cyclizations of iodonium ylides with alkynes

Hao Liang et al. Chem Commun (Camb). .

Abstract

The copper(ii)-catalyzed (4+1) cyclizations and copper(i)-catalyzed (3+2) cycloadditions of iodonium ylides and alkynes were successfully developed by employing efficient and safe iodonium ylides instead of traditional diazo compounds. Highly functionalized dimethyl (E)-3-benzylideneindoline-2,2-dicarboxylates and methyl 5-(2-hydroxyphenyl)-2-methoxy-4-phenylfuran-3-carboxylates were conveniently prepared in moderate to excellent yields. The possible reaction mechanisms were also discussed.

PubMed Disclaimer

LinkOut - more resources