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Review
. 2020 Oct;32(40):e2002366.
doi: 10.1002/adma.202002366. Epub 2020 Aug 30.

Structural Approaches to Control Interlayer Interactions in 2D Covalent Organic Frameworks

Marta Martínez-Abadía  1 , Aurelio Mateo-Alonso  1   2
Affiliations
Review

Structural Approaches to Control Interlayer Interactions in 2D Covalent Organic Frameworks

Marta Martínez-Abadía et al. Adv Mater. 2020 Oct.

Abstract

The ability to design and synthesize monomers can affect fundamental aspects in 2D covalent organic frameworks, such as dimensionality, topology, and pore size. Besides this, the structure of the monomers can also affect interlayer interactions, which provide an additional means to influence crystallinity, layer arrangement, interlayer distances, and exfoliability. Herein, some of the effects that the structure of monomers can have on the interlayer interactions in 2D covalent organic frameworks and related materials are illustrated.

Keywords: 2D polymers; covalent organic frameworks; interlayer interactions.

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