Catalytic Activation of Cobalt Doping Sites in ZIF-71-Coated ZnO Nanorod Arrays for Enhancing Gas-Sensing Performance to Acetone

Abstract

Developing acetone gas sensors with high sensitivity is crucially important for many applications including nonevasive diagnosis of diabetes. In the present work, cobalt doping is used to catalyze acetone gas-sensing reactions and hence to promote the sensitivity of acetone gas sensors. In order to achieve this, ZIF-71 metal-organic framework (MOF) is synthesized onto ZnO nanorod arrays with various concentrations of Co doping to form composite ZnO@ZIF-71(Co) sensors, which are then evaluated as sensing materials for acetone detection. Such sensors are shown to be sensitive to a trace amount of acetone (50 ppb) and have a massively enhanced response of about 100 times that for the undoped sensor at an optimal Co/Zn ratio and operating temperature. Fourier-transform infrared spectroscopy and temperature-programmed desorption with density functional theory calculations are also made to assist in elucidating the catalytic gas-sensing mechanism for the Co-doped composite sensors ZnO@ZIF-71(Co). It demonstrated that the introduced Co site in ZIF-71(Co) can activate oxygen catalytically and increase active oxygen released to the ZnO surface. Meanwhile, the Co sites also promote the decomposition of acetone. These two steps together affect the catalytic oxidation of gases and finally enhance the sensitivity. This work introduces the catalytic effect of the MOF into the gas-sensing mechanism and provides an idea for broadening the application of MOF catalysis.

Keywords: DFT calculations; acetone decomposition; acetone gas sensor; catalytic activity; cobalt-doped MOF.