Emerging Chemical Functionalization of g-C3N4: Covalent/Noncovalent Modifications and Applications

Abstract

Atomically 2D thin-layered structures, such as graphene nanosheets, graphitic carbon nitride nanosheets (g-C₃N₄), hexagonal boron nitride, and transition metal dichalcogenides are emerging as fascinating materials for a good array of domains owing to their rare physicochemical characteristics. In particular, graphitic carbon nitride has turned into a hot subject in the scientific community due to numerous qualities such as simple preparation, electrochemical properties, high adsorption capacity, good photochemical properties, thermal stability, and acid-alkali chemical resistance, etc. Basically, g-C₃N₄ is considered as a polymeric material consisting of N and C atoms forming a tri-s-triazine network connected by planar amino groups. In comparison with most C-based materials, g-C₃N₄ possesses electron-rich characteristics, basic moieties, and hydrogen-bonding groups owing to the presence of hydrogen and nitrogen atoms; therefore, it is taken into account as an interesting nominee to further complement carbon in applications of functional materials. Nevertheless, g-C₃N₄ has some intrinsic limitations and drawbacks mainly related to a relatively poor specific surface area, rapid charge recombination, a limited light absorption range, and a poor dispersibility in both aqueous and organic mediums. To overcome these shortcomings, numerous chemical modification approaches have been conducted with the aim of expanding the range of application of g-C₃N₄ and enhancing its properties. In the current review, the comprehensive survey is conducted on g-C₃N₄ chemical functionalization strategies including covalent and noncovalent approaches. Covalent approaches consist of establishing covalent linkage between the g-C₃N₄ structure and the chemical modifier such as oxidation/carboxylation, amidation, polymer grafting, etc., whereas the noncovalent approaches mainly consist of physical bonding and intermolecular interaction such as van der Waals interactions, electrostatic interactions, π-π interactions, and so on. Furthermore, the preparation, characterization, and diverse applications of functionalized g-C₃N₄ in various domains are described and recapped. We believe that this work will inspire scientists and readers to conduct research with the aim of exploring other functionalization strategies for this material in numerous applications.

Keywords: 2D materials; chemical modification; covalent; dispersibility; functionalization; g-C3N4; heterostructure; noncovalent; photocatalysis; polymer grafting.