Dual-functional micro-adsorbents: Application for simultaneous adsorption of cesium and strontium

Abstract

In current work, Prussian blue (PB)- and hydroxyapatite (HAp)-embedded micro-adsorbents (PB-HAp-MAs) were rationally fabricated through an easy and flexible custom-made micronozzle system as a novel bifunctional adsorbent. The adsorption performance of the as-prepared samples was conducted based on the removal of cesium (Cs⁺) and strontium (Sr²⁺) ions. Adsorption behaviors of the PB-HAp-MAs were also evaluated as function extrusion dimensions and adsorbate concentration. The adsorption isotherm was well fitted by the Langmuir model with adsorption capacities of 24.688 mg g^-1 and 29.254 mg g^-1 for Cs⁺ and Sr²⁺, respectively. Specially, the enhanced adsorption activity can be synergistically attributed to the porous nature of the developed alginate backbone with a high surface area of encapsulated functional nanoparticles, thus leading to rapid saturation within 1 min. In addition, the as-synthesized PB-HAp-MAs were successfully separated from the aqueous solution within 10 s by applying a magnetic field. We expect that our findings will provide valuable guidelines towards developing highly efficient adsorbents for environmental remediation.

Keywords: Cesium; Hydroxyapatite; Micro-adsorbent; Micronozzle system; Prussian blue; Strontium.