Superspreading - Has the mystery been unraveled?

Abstract

Superspreading is a fascinating phenomenon first observed about 30 years ago with dilute solutions of trisiloxane surfactants on hydrophobic substrates. Although many groups all over the world have contributed considerably to solve the scientific challenges involved, the reasons why only some trisiloxane surfactants promote superspreading, whereas others of similar chemical structure behave more like ordinary surfactants, has remained a mystery up to now. A number of original papers and reviews on superspreading have been published in recent years. The driving force still proposed today is most often Marangoni flow. This is, however, in contradiction with recent results showing that superspreading only starts after a surface tension gradient between apex and leading edge has been eliminated. From foam film experiments unrelated to wetting, there is evidence for "dangling" bilayers attached to the air/water interface only in case of the superspreading trisiloxane surfactants. By combining this and other published experimental findings, a new hypothesis of the mode of action is put forward: Advancing by "rolling action" at the leading edge, and the supply of surfactant by "unzippering" of the dangling bilayers all over the surface of the drop; this hypothesis even fulfills basic thermodynamic requirements.

Keywords: Complete wetting; Marangoni; Mode of action; Superspreading; Trisiloxane surfactant.