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. 2021 Jan 20;143(2):681-686.
doi: 10.1021/jacs.0c12134. Epub 2021 Jan 6.

Thermal Cycling of a MOF-Based NO Disproportionation Catalyst

Ashley M Wright  1 , Chenyue Sun  1 , Mircea Dincă  1
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Thermal Cycling of a MOF-Based NO Disproportionation Catalyst

Ashley M Wright et al. J Am Chem Soc. .

Abstract

The metal-organic framework CuI-MFU-4l reacts with NO, initially forming a copper(I)-nitrosyl at low pressure, and subsequently generates NO disproportionation products CuII-NO2 and N2O. The thermal stability of MFU-4l allows NOx to be released from the framework at temperatures greater than 200 °C. This treatment regenerates the original CuI-MFU-4l, which can engage in subsequent cycles of NO disproportionation.

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