Comparison of poly ferric chloride and poly titanium tetrachloride in coagulation and flocculation process for paper and cardboard wastewater treatment

Abstract

The current study investigated the efficiency of poly ferric chloride (PFC) and poly titanium tetrachloride (PTC) in coagulation-flocculation process for treatment of paper and cardboard wastewater. The effect of pH (5-11), coagulant concentrations (100-1000 mg/L), mixing rate (10-60 rpm), mixing time (5-25 min), and settling time (5-30 min) were examined. The results showed that the removal efficiency for turbidity, total suspended solids (TSS), and chemical oxygen demand (COD) by PFC and PTC coagulants increased with pH rising up to 9 for the former and 7 for the latter coagulant. Furthermore, the removal efficiency for the afore-mentioned parameters increased along with a 30 rpm increase in the mixing rate, while the mixing time reached 20 min. It was also found that the best removal efficiencies for turbidity, TSS, and COD by PFC under optimal conditions (pH 9, coagulant dose 800 mg/L, and settling time of 25 min) were 97.11%, 99.1%, and 84.91%, respectively. In addition, the removal efficiencies for PTC (optimal conditions of pH 7, coagulant dose 600 mg/L, and settling time of 15 min) were found to be 98.29%, 99.29%, and 86.42%, respectively. Water recovery and the produced sludge volume by PFC were 80% and 200 cm³, respectively, in the settling time of 25 min and for PTC were 81.5% and 185 cm³, respectively, in the settling time of 15 min. Costs of the coagulation-flocculation process for treatment 1 m³ of paper and cardboard wastewater using PTC and PFC were 0.42 $ and 0.32 $, respectively. Finally, it can be concluded that compared to PFC, PTC with higher settling rate has a greater efficiency for treatment of paper and cardboard wastewater.

Keywords: COD removal; Coagulation/flocculation; Industrial wastewater; Paper and cardboard industries; Polymeric coagulant; Wastewater treatment.